Realizing high thermoelectric performance of Cu and Ce co-doped p-type polycrystalline SnSe via inducing nanoprecipitation arrays
نویسندگان
چکیده
Abstract Thermoelectric (TE) performance of polycrystalline stannous selenide (SnSe) has been remarkably promoted by the strategies energy band, defect engineering, etc. However, due to intrinsic insufficiencies phonon scattering and carrier concentration, it is hard simultaneously realize regulations electrical thermal transport properties one simple approach. Herein, we develop Cu Ce co-doping strategy that can not only greatly reduce lattice conductivity but also improve properties. In this strategy, incorporated atoms could induce high-density SnSe2 nanoprecipitation arrays on surface SnSe microplate, produce dopant atom point defects dislocations in its interior, which form multi-scale synergy, thereby presenting an ultralow 0.275 W·m -1 ·K at 786 K. Meanwhile, density functional theory (DFT) calculations, mobility testing reveal more extra hole carriers lower conducting generate after co-doping, improving conductivity. The co-doped Sn 0.98 0.01 Se bulk exhibits excellent ZT value up ~1.2 K a high average 0.67 from 300 This work provides convenient enhancing TE SnSe.
منابع مشابه
Enhanced Thermoelectric Properties of Polycrystalline SnSe via LaCl3 Doping
LaCl₃ doped polycrystalline SnSe was synthesized by combining mechanical alloying (MA) process with spark plasma sintering (SPS). It is found that the electrical conductivity is enhanced after doping due to the increased carrier concentration and carrier mobility, resulting in optimization of the power factor at 750 K combing with a large Seebeck coefficient over 300 Μvk-1. Meanwhile, all the s...
متن کاملInvestigation of the Anisotropic Thermoelectric Properties of Oriented Polycrystalline SnSe
Polycrystalline SnSe was synthesized by a melting-annealing-sintering process. X-ray diffraction reveals the sample possesses pure phase and strong orientation along [h00] direction. The degree of the orientations was estimated and the anisotropic thermoelectric properties are characterized. The polycrystalline sample shows a low electrical conductivity and a positive and large Seebeck coeffici...
متن کاملUltrahigh power factor and thermoelectric performance in hole-doped single-crystal SnSe.
Thermoelectric technology, harvesting electric power directly from heat, is a promising environmentally friendly means of energy savings and power generation. The thermoelectric efficiency is determined by the device dimensionless figure of merit ZT(dev), and optimizing this efficiency requires maximizing ZT values over a broad temperature range. Here, we report a record high ZT(dev) ∼1.34, wit...
متن کاملRealizing high figure of merit in heavy-band p-type half-Heusler thermoelectric materials
Solid-state thermoelectric technology offers a promising solution for converting waste heat to useful electrical power. Both high operating temperature and high figure of merit zT are desirable for high-efficiency thermoelectric power generation. Here we report a high zT of ∼1.5 at 1,200 K for the p-type FeNbSb heavy-band half-Heusler alloys. High content of heavier Hf dopant simultaneously opt...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Advanced Ceramics
سال: 2022
ISSN: ['2227-8508', '2226-4108']
DOI: https://doi.org/10.1007/s40145-022-0639-6